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The Synthesis of Porous Na3V2(PO4)3 for Sodium-Ion Storage
Authors:Dr Hailong Xiong  Chunyu Qi  Prof Shiquan Lv  Prof Ling Zhang  Prof Zhen-An Qiao
Institution:1. Department State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin, 130012 P. R. China

Hefei National Laboratory for Physical Sciences at the Microscale, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), University of Science and Technology of China, Hefei, 230026 P. R. China;2. Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Changchun, 130103 P. R. China;3. State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, 130012 P. R. China;4. Department State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin, 130012 P. R. China

Abstract:Na3V2(PO4)3 (NVP) has been regarded as a potential cathode material for sodium-ion batteries (SIBs) due to its excellent structural stability and rapid Na+ conductivity. However, its electrochemical performances are restricted by the large bulk structure and poor electronic conductivity. The construction of porous NVP materials is a powerful method to improve the electrochemical properties. This concept aims to provide an overview of recent progress of porous NVP materials for SIBs. Herein, the synthetic strategies and formation mechanisms of porous NVP materials as well as the relationship between the porous structures and electrochemical performances of NVP materials are reviewed. Furthermore, the challenges and prospects for the preparation of porous NVP materials in this field are outlined.
Keywords:energy storage  fuel cells  porous materials  sodium-ion batteries
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