| 苯基乙酰甲基亚砜与碱土金属配合物的合成和晶体结构(英) |
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| 引用本文： | 李文先,王宏胜,胡瑞珏,其其格.苯基乙酰甲基亚砜与碱土金属配合物的合成和晶体结构(英)[J].无机化学学报,2005,21(9):1291-1295. |
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| 作者姓名： | 李文先 王宏胜 胡瑞珏 其其格 |
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| 作者单位： | 内蒙古大学化学化工学院,呼和浩特,010021 |
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| 基金项目： | 内蒙古自然科学基金(No.200308020104)，内蒙古教育厅科研基金(No.NJ322002)，内蒙古大学“513”二层次人才基金 |
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| 摘 要： | 本文选取苯基乙酰甲基亚砜(C6H5SOCH2COCH3)作为配体与碱土金属(钙、锶)的高氯酸盐反应得到配合物的单晶，对它们进行了元素分析及红外光谱表征，它们的化学式为ML6](ClO4)2(M=Ca、Sr；L=C6H5SOCH2COCH3)。并用X-ray单晶衍射法测定了钙、锶配合物的晶体结构。
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| 关 键 词： | 碱土金属 X-ray晶体结构 苯基乙酰甲基亚砜 |
| 文章编号： | 1001-4861(2005)09-1291-05 |
| 收稿时间： | 2004-12-02 |
| 修稿时间： | 6/2/2005 12:00:00 AM |
Synthesis and Crystal Structure of Phenyl-acetyl Methylene Sulfoxide Complexes with Alkaline-Earth Metal |
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| LI Wen-Xian,WANG Hong-Shneg,HU Rui-Jue and QI Qi-Ge.Synthesis and Crystal Structure of Phenyl-acetyl Methylene Sulfoxide Complexes with Alkaline-Earth Metal[J].Chinese Journal of Inorganic Chemistry,2005,21(9):1291-1295. |
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| Authors: | LI Wen-Xian WANG Hong-Shneg HU Rui-Jue and QI Qi-Ge |
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| Institution: | College of Chemistry & chemical Engineering, Inner Mongolia University, Huhhot 010021,College of Chemistry & chemical Engineering, Inner Mongolia University, Huhhot 010021,College of Chemistry & chemical Engineering, Inner Mongolia University, Huhhot 010021 and College of Chemistry & chemical Engineering, Inner Mongolia University, Huhhot 010021 |
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| Abstract: | Two complexes of alkaline-earth metals perchlorate with phenyl-acetylmethylene sulfoxide(C6H5SOCH2COCH3) have been synthesized and characterized by elemental analysis and IR spectra. Composition of complexes are ML6](ClO4)2(M=Ca, Sr; L=C6H5SOCH2COCH3). The crystal structures of the complexes of Ca and Sr were determined by X-ray single crystal diffraction analysis. CCDC: 23880 (Ca); 23881 (Sr). |
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| Keywords: | alkaline-earth metals X-ray crystal structure phenyl-acetylmethylene sulfoxide |
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