First trinuclear paramagnetic transition metal complexes with redox active ligands derived from TTF: Co2M(PhCOO)6(TTF-CH=CH-py)2.2CH3CN, M = CoII, MnII |
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| Authors: | Gavrilenko Konstantin S Gal Yann Le Cador Olivier Golhen Stéphane Ouahab Lahcène |
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| Institution: | Organométalliques et Matériaux Moléculaires, UMR 6226 CNRS-UR1 Sciences Chimiques de Rennes, Université de Rennes 1, 35042, Rennes Cedex, France. |
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| Abstract: | The first paramagnetic homo- and hetero-metallic trinuclear complexes with redox active ligands derived from TTF are synthesized, the central metal ion has an octahedral coordination sphere while the outer Co(II) ions are in a distorted bipyramidal surrounding, bearing TTF-ligands, the magnetic properties show antiferromagnetic coupling leading to a magnetic ground state. |
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