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A Closed‐Loop Phase Diagram in a Weakly Interacting Polyolefin Copolymer Binary Blend System
Authors:Haiqing Hu  Chuanbo Chong  Aihua He  Chenggui Zhang  Guoqiang Fan  Jin‐Yong Dong  Charles C Han
Abstract:Summary: The phase behavior of poly(ethylene‐co‐styrene) (PES) and poly(ethylene‐co‐butene) (PEB) blends has been studied. A closed‐loop phase diagram was clearly observed in this weakly interacting system as the styrene content in the PES decreased to about 1 mol‐%. At higher styrene contents, the phase loop starts to interplay with the crystallization transformation at lower temperatures.
image

Phase diagram of PEB/PES blends. Phase boundary line is only for easy demonstration.

Keywords:closed‐phase loop  PEB  PES  phase diagrams  weakly interacting binary polymer system
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