| Abstract: | 2‐Benzothiazolyl‐N‐(arenesulfonyl)‐sulfinimidoyl fluorides were synthesized by the treatment of benzothiazolyl‐2‐sulfur trifluoride with sulfonamides. The reaction of 2‐benzothiazolyl‐N‐ (p‐toluenesulfonyl)‐sulfinimidoyl fluoride with tert‐ butylamine and morpholine gave 2‐benzothiazolyl‐ N‐(arenesulfonyl)‐sulfinimidoyl amides. The reaction of 2‐benzothiazolyl‐N‐(p‐toluenesulfonyl)‐sulfinimi‐ doyl fluoride or 2‐benzothiazolyl‐15N‐(p‐tosyl)sul‐ finimidoyl fluoride with S‐trimethylsilylbenzenethiol gave di(benzothiazolyl‐2) disulfide, fluorotrimethylsi‐ lane and N,N′‐bis(p‐toluenesulfonyl)‐N,N′‐bis(phenyl‐ thio)‐hydrazine or 15N,15N′‐bis(p‐toluenesulfonyl)‐15N, 15N′‐bis(phenylthio)‐hydrazine, respectively. © 2005 Wiley Periodicals, Inc. Heteroatom Chem 16:352–356, 2005; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20102 |
