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Supramolecular Assembly of Gold Nanoparticles Mediated by Polypseudorotaxane with Thiolated β‐Cyclodextrin
Authors:Yu Liu  Yan‐Li Zhao  Yong Chen  Min Wang
Abstract:Summary: A water‐soluble gold nanoparticle aggregate 2 was prepared by chloroauric acid and a polypseudorotaxane 1 of mono‐6‐thio‐β‐cyclodextrin with poly(propylene glycol) bis(2‐aminopropyl ether) (equation image ≈ 2 000) in the presence of sodium borohydride in N,N‐dimethylformamide (DMF) solution. The investigative results indicated that the gold nanoparticle aggregate 2 might act as an efficient DNA‐cleavage reagent.
image

A typical TEM image of gold nanoparticle aggregate 2 .

Keywords:cyclodextrin  nanoparticles  polypseudorotaxane  self‐assembly  supramolecular structure
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