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Robust Poly(allylamine)‐graft‐poly(N‐isopropylacrylamide) Particles Prepared by Physical Crosslinking with Poly(styrene sulfonate)
Authors:Bo Chen  Changyou Gao
Abstract:Summary: Robust thermosensitive PAH‐g‐PNIPAAm/PSS particles were prepared by addition of a poly(allylamine)‐graft‐poly(N‐isopropylacrylamide) particle suspension into poly(styrene sulfonate) solution above the LCST of PAH‐g‐PNIPAAm. Scanning force microscopy revealed stable and well‐separated particles in water at room temperature. The zeta‐potential showed a negative surface charge of the particles. Their thermosensitive behavior was demonstrated by dynamic light scattering. The release of rhodamine 6G loaded particles could respond to the incubation temperature.

Fabrication of thermosensitive and robust particle by suspension of in situ formed PAH‐g‐PNIPAAm particle above the LCST in PSS solution.

Keywords:crosslinking  particles  polyelectrolytes  poly(N‐isopropylacrylamide)  thermosensitive
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