Redoxkinetik von Metallkomplexen in nichtwäßrigen Lösungen,XI. Die Reduktion von Thallium(III)oxinat mit Eisen(II) in schwach koordinierenden Lösungsmitteln |
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Authors: | Rudolf W Soukup Valentin N Sapunov Hossein Ateshykashi Roland Schmid |
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Institution: | 1. Institut für Anorganische Chemie, Technische Universit?t Wien, A-1060, Wien, ?sterreich 2. Chemisch-Technologisches Mendeleev-Institut, Moskau, UdSSR
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Abstract: | The kinetics of the iron(II) reduction of thallium(III) oxinate does not differ essentially from that of the oxinate-transfer from thallium(III)-oxinate to iron(III), described before: formation of a binuclear intermediate, rearrangements within, and subsequent reaction with the excess reactant to the final products. As for the redox process, these intermediates are binuclear Tl(II)-Fe(III) complexes which, with initial reactants, form further complexes in which the second electron is transferred. In the cases of excess Tl(ox)3 and of equimolar reactants, disproportionations are likely involved. |
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