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Ligand-Promoted [Pd]-Catalyzed α-Alkylation of Ketones through a Borrowing-Hydrogen Approach |
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| Authors: | Dr Seetharaman Manojveer Nitish K Garg Zarif Gul Ayesha Kanwal Dr Yogesh Goriya Dr Magnus T Johnson |
| Institution: | Centre for Analysis and Synthesis, Department of Chemistry, Lund University, P. O. Box 124, 221 00 Lund, Sweden |
| Abstract: | A new class of palladium complexes bearing bidentate 2-hydroxypyridine based ligands have been prepared and fully characterized. The applications of these new complexes towards ketone alkylation reactions with alcohols through a metal-ligand cooperative borrowing-hydrogen (BH) process were demonstrated. |
| Keywords: | α-alkylation borrowing-hydrogen catalysis 2-hydroxypyridine MLC |