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Natural source compatibilizers for olive waste/recycled polypropylene matrix composites
Authors:Zohar Rapoport  Galy Levy  Ana Dotan
Affiliation:Department of Polymer Materials Engineering, Shenkar Engineering, Design. Arts., Ramat Gan, Israel
Abstract:A simple, environmentally friendly process was developed for surface hydrophobization of cellulose-rich waste to improve their compatibility with recycled polypropylene (rPP), helping reduce costs while recycling environmentally problematic waste such as solid olive waste (also called olive pomace). In this study, an improvement of the interfacial bonding strength between the hydrophilic waste particles and the hydrophobic matrix was achieved by surface hydrophobization of the waste using a ring-opening polymerization reaction of epoxidized soy-bean oil (ESBO) with SnCl2 as a catalyst. The treatment on cellulose based filter paper led to a contact angle of 128°. The composite containing treated olive pomace has shown an increase in the elongation of 92% and an increase in the stress at yield of 15%, indicating improved compatibility.
Keywords:compatibilizer  environmentally friendly  epoxidized soy-bean oil  lignocellulose  olive waste  recycling  ring-opening polymerization
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