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Recent progress in measurements of oscillatory forces and liquid properties under confinement
Institution:1. Beijing Key Laboratory of Ionic Liquids Clean Process, CAS Key Laboratory of Green Process and Engineering, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, CAS, Beijing, 100190, China;2. Department of Materials and Environmental Chemistry, Arrhenius Laboratory, Stockholm University, SE-10691 Stockholm, Sweden;3. State Key Laboratory of Materials-Oriented and Chemical Engineering, Nanjing Tech University, Nanjing, 210009, China;4. Centre of Advanced Research in Bionanoconjugates and Biopolymers, Petru Poni Institute of Macromolecular Chemistry, Aleea Grigore Ghica-Voda, 41A, 700487 Iasi, Romania;5. Department of Engineering Sciences and Mathematics, Division of Energy Science, Luleå University of Technology, SE-97187 Luleå, Sweden
Abstract:The present review paper focuses on direct measurements of oscillatory forces. Beside the surface forces apparatus (SFA), atomic force microscopy (AFM) has emerged as the most commonly used technique to measure surface forces. Recent instrumental advances of both methods are highlighted in the review. Different systems, showing oscillatory forces are classified. Principle distinction is made between 1-component liquids (water, organic liquids and liquid crystals), pseudo 1-component liquids (ionic liquids and microemulsions) and 2-component liquids (dispersions containing polyelectrolytes, micelles or nanoparticles). In the last few years, the oscillatory force studies address particle characterisation, synergistic effects in multicomponent systems, the introduction of ‘switchable’ forces, and resolving liquid properties under confinement. Last but not least, the ability of AFM and SFA to measure oscillatory forces is discussed.
Keywords:Oscillatory force  Structural force  Solvation force  Depletion force  Structure formation under confinement  Direct force measurements  Atomic force microscopy  Surface forces apparatus
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