Stereoselective Synthesis of Isomers of the Naturally Occurring 13-Hydroxy-2,4,9-tetradecatrienoic Acid. Part II [1] |
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| Authors: | Email author" target="_blank">Antje?HuefnerEmail author Christa?Hoeller Gottfried?Reznicek |
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| Institution: | (1) Institute of Pharmaceutical Chemistry and Pharmaceutical Technology, University of Graz, A-8010 Graz, Austria;(2) Institute of Pharmacognosy, University of Vienna, PharmaCenter Vienna, A-1090 Wien, Austria |
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| Abstract: | Summary. The stereoselective syntheses of four unsaturated hydroxy fatty acids 13S,2E,4E,9E)- 13-hydroxy-2,4,9-tetradecatrienoic acid, (13S,9Z,11E)-13-hydroxy-9,11-tetradecadienoic acid, (13S,9E, 11E)-13-hydroxy-9,11-tetradecadienoic acid, and (13S,2E,4E,9E)-13-hydroxy-2,4,9,11-tetradecatrienoic acid, are described. Wittig reactions, regioselective oxidation of dialcohol 3, and diastereomerization were used. |
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| Keywords: | , Fatty acid, Aldehydes, Wittig Reaction, (Z,E)-Isomerization, |
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