| 二维镉配位聚合物[Cd(nip)(bix)0.5H2O]n构筑的新型(3，5，5)连接的三维氢键超分子体系 |
| |
| 引用本文： | 胡宗智,赵 君,柯希俊,何秋芬,李 彩,李东升.二维镉配位聚合物[Cd(nip)(bix)0.5H2O]n构筑的新型(3，5，5)连接的三维氢键超分子体系[J].无机化学学报,2011,27(1):184-188. |
| |
| 作者姓名： | 胡宗智 赵 君 柯希俊 何秋芬 李 彩 李东升 |
| |
| 作者单位： | 三峡大学机械与材料学院,功能材料研究所,宜昌,443002 |
| |
| 基金项目： | 国家自然科学基金，湖北省自然科学基金，湖北省教育厅重大基金，青年人才基金 |
| |
| 摘 要： | 在水热条件下合成了一个新颖的配位聚合物Cd(nip)(bix)0.5H2O]n (1) (nip=5-硝基间苯二甲酸，bix=1，4-(二亚甲基)二咪唑)。单晶X-射线衍射分析表明，晶体属三斜晶系，P1 空间群，晶胞参数a=0.827 1(2) nm，b=1.016 5(3) nm，c=1.147 4(3) nm，α=70.862(4)°，β=68.988(4)°，γ=69.001(4)°。V=0.818 4(4)nm3，Z=2，Dc=1.861g·cm-3，μ=1.380 mm-1，F(000)=454，最终的R1=0.040 0，wR2=0.090 1。配合物1中，nip2-离子以μ3桥联的方式连接Cd(Ⅱ)中心形成含有交替8元环和16元环的一维聚合链，进而，bix配体柱撑一维链形成了(3，4)-连接的二维配位网；最后，通过R22(6)氢键环的作用，二维网拓展为具有(3，5，5)-连接{3.4.5}{3.42.5.64.7.8} {3.43.52.62.72}拓扑结构的三维超分子体系。此外，本文还研究了配合物1的热稳定性和荧光性质。
|
| 关 键 词： | 镉(Ⅱ)配合物 晶体结构 氢键 拓扑 |
A Novel 3D (3,5,5)-Connected H-bonding Architecture Based on 2D Coordination Polymer [Cd(nip)(bix)0.5H2O]n |
| |
| HU Zong-Zhi,ZHAO Jun,KE Xi-Jun,HE Qiu-Fen,LI Cai and LI Dong-Sheng.A Novel 3D (3,5,5)-Connected H-bonding Architecture Based on 2D Coordination Polymer [Cd(nip)(bix)0.5H2O]n[J].Chinese Journal of Inorganic Chemistry,2011,27(1):184-188. |
| |
| Authors: | HU Zong-Zhi ZHAO Jun KE Xi-Jun HE Qiu-Fen LI Cai and LI Dong-Sheng |
| |
| Institution: | College of Mechanical & Material Engineering, Functional Materials Research Institute, China Three Gorges University, Yichang, Hubei 443002, China,College of Mechanical & Material Engineering, Functional Materials Research Institute, China Three Gorges University, Yichang, Hubei 443002, China,College of Mechanical & Material Engineering, Functional Materials Research Institute, China Three Gorges University, Yichang, Hubei 443002, China,College of Mechanical & Material Engineering, Functional Materials Research Institute, China Three Gorges University, Yichang, Hubei 443002, China,College of Mechanical & Material Engineering, Functional Materials Research Institute, China Three Gorges University, Yichang, Hubei 443002, China and College of Mechanical & Material Engineering, Functional Materials Research Institute, China Three Gorges University, Yichang, Hubei 443002, China |
| |
| Abstract: | A novel compound Cd (nip) (bix)o,5H20]n (1) (nip =5-nitroisophthalic acid and bix=1,4-bis (imidazol-l-ylmethyl)-benzene) has been hydrothermally prepared and characterized. Single-crystal X-ray diffraction studies indicate that the compound 1 crystallizes in triclinic, space group PI with a=0.8271(2) nm, b=1.0165(3) nm, c=1.147 4(3) nm, α=70.862(4)°,β=68.988(4)°,γ=69.001(4)°,γ=0.8184(4)nm~3 , Z=2 , D_c=1.861g·cm~3,μ=1.380 mm~(-1)F(000)=454 , and final R,=0.040 0, wR2=0.090 1. In 1, nip' ions act as ,u.3-linker to bridge Cd n atoms into an infinite 1D chain with alternately 8-member ring and 16-member ring, moreover, the bix ligands pillar these 1D chains into 2D (3,4)-connected coordination network. Eventually, through R22(6) H-bonding rings, these 2D nets are extended to 3D supramolecular framework showing a new (3,5,5)-connected (3.4.5) (3.4~2.5.6~4.7.8)｛3.4~3.5~2.6~2.7~2｝topology. In addition, the thermal and fluorescence properties associated with the compound 1 were also investigated. |
| |
| Keywords: | Cd(Ⅱ) complex crystal structure H-bonding topology |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
