The Preparation, Characterization and X-ray Structural Analysis of Tetrakis[1-Methyl-3-(2-Propyl)-2(3H)-Imidazolethione]Cadmium(II) Hexafluorophosphate |
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Authors: | Daniel J Williams Daniel Gulla Kimberly A Arrowood Lindsey M Bloodworth Angela L Carmack Taylor J Evers Mark S Wilson Javier J Concepcion Carol A S Brevett Benjamin E Huck Donald VanDerveer |
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Institution: | (1) Department of Chemistry and Biochemistry, Kennesaw State University, Kennesaw, GA 30144, USA;(2) SAIC, P.O. Box 68, Gunpowder Branch, Aberdeen Proving Ground, MD 21010, USA;(3) Department of Chemistry, Clemson University, Clemson, SC 29634, USA |
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Abstract: | Abstract A new compound, Cd(mipit)4]PF6]2 has been synthesized and characterized via standard solid and solution state methods including single crystal X-ray crystallography
(mipit = 1-methyl-3-(2-propyl)-2(3H)-imidazolethione). The title compound crystallizes in tetragonal space group I4
1
/a with a = 12.478(2) ?, b = 12.478(2) ?, c = 28.806(6) ?, and Z = 4. The complex is a high melting, colorless solid that has a distorted tetrahedral CdS4 coordination geometry. Thermogravimetric analysis results for the title compound as well as for another potential CdS synthon
and two potential CdSe synthons are reported.
Graphical Abstract The synthesis and characterization of the title compound, a new ionic homoleptic cadmium complex, tetrakis1-methyl-3-(2-propyl)-2(3H)-imidazolethione]cadmium(II)
hexafluorophosphate is reported. The results of a single crystal X-ray diffraction analysis reveal a distorted tetrahedral
CdS4 coordination sphere about the cadmium.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. |
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Keywords: | X-ray crystallography Cadmium complex Alkylimidazolethione Heteroleptic complex Homoleptic complex Thermogravimetric analysis |
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