Oxopentacyano-complexes of molybdenum(IV) and tungsten(IV) in photolysis of octacyanometalates(IV) |
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| Authors: | Magdalena Dudek Alina Samotus |
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| Institution: | (1) Department of Chemistry, Jagiellonian University, Kraków, Poland |
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| Abstract: | Summary Ligand-field (LF) photolysis of aqueous alkaline solutions of K4M(CN)8] (M = Mo or W) containing KCN produces MO(CN)5]3– species. NaCs2]MO(CN)5] was isolated and characterised by u.v.-vis., i.r. and Raman spectroscopy. In addition, the reactions of MO(OH)(CN)4]3– with free CN– are described and the relations between octa-, penta- and tetra-cyanocomplexes are summarised. |
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