Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo(11)V(7)}: [Mo(VI)(11)V(V)(5)V(IV)(2)O(52)(mu(9)-SO(3))](7-) |
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| Authors: | Miras Haralampos N Stone Daniel J McInnes Eric J L Raptis Raphael G Baran Peter Chilas George I Sigalas Michael P Kabanos Themistoklis A Cronin Leroy |
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| Institution: | WestCHEM, Department of Chemistry, The University of Glasgow, Glasgow, Scotland, UK G12 8QQ. |
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| Abstract: | A polyoxomolybdenum/vanadium-sulfite {M(18)} cluster-based compound, Mo(VI)(11)V(V)(5)V(IV)(2)O(52)(mu(9)-SO(3))](7-), is reported that exhibits a unique structural motif, arising from the incorporation of five V(V) and two V(IV) ions into a {M(18)} cluster framework templated by SO(3)(2-); this cluster compostion was first identified using cryospray mass spectrometry. |
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