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Simultaneous enzymatic ring opening polymerisation and RAFT-mediated polymerisation in supercritical CO2
Authors:Thurecht Kristofer J  Gregory Andrew M  Villarroya Silvia  Zhou Jiaxiang  Heise Andreas  Howdle Steven M
Affiliation:School of Chemistry, University of Nottingham, University Park, Nottingham, UK. steve.howdle@nottingham.ac.uk
Abstract:This report presents the first simultaneous, metal-free synthesis of block copolymers through combination of enzymatic ring-opening polymerisation of epsilon-caprolactone with RAFT-mediated controlled radical polymerisation of styrene.
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