Simultaneous enzymatic ring opening polymerisation and RAFT-mediated polymerisation in supercritical CO2 |
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Authors: | Thurecht Kristofer J Gregory Andrew M Villarroya Silvia Zhou Jiaxiang Heise Andreas Howdle Steven M |
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Affiliation: | School of Chemistry, University of Nottingham, University Park, Nottingham, UK. steve.howdle@nottingham.ac.uk |
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Abstract: | This report presents the first simultaneous, metal-free synthesis of block copolymers through combination of enzymatic ring-opening polymerisation of epsilon-caprolactone with RAFT-mediated controlled radical polymerisation of styrene. |
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