Cycloaddition reactions of transition metal hydrazides with alkynes and heteroalkynes: coupling of Ti=NNPh2 with PhCCMe, PhCCH, MeCN and tBuCP |
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| Authors: | Selby Jonathan D Schulten Christian Schwarz Andrew D Stasch Andreas Clot Eric Jones Cameron Mountford Philip |
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| Institution: | Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, UKOX1 3TA. |
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| Abstract: | The first structurally authenticated 2+2] cycloaddition products of any transition metal hydrazide complexes are reported; cycloaddition products of transition metal hydrazides with alkynes and heteroalkynes have been obtained for the first time; these are the first structurally authenticated cycloaddition products for any transition metal M=NNR(2) functional group. |
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