Palladium-catalyzed carboboration of alkynes using chloroborane and organozirconium reagents |
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| Authors: | Daini Masaki Suginome Michinori |
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| Affiliation: | Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University Katsura, Nishikyo-ku, Kyoto 615-8510, Japan. |
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| Abstract: | Three-component coupling of bis(dialkylamino)chloroborane, alkynes and organozirconium reagents proceeded in the presence of palladium catalysts, leading to the formation of stereo-defined alkenylborane derivatives via cis-carboboration of carbon-carbon triple bonds. |
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