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Electrical transport and magnetic ordering in R 2Ti3Ge4 (R=Dy, Ho and Er) compounds
Authors:R Nirmala  V Sankaranarayanan  K Sethupathi  AV Morozkin  T Geethakumary  Y Hariharan
Institution:(1) Department of Physics, Indian Institute of Technology, 600 036 Chennai, India;(2) Chemical Faculty, Moscow Lomonosov State University, Moscow, Russia;(3) Material Sciences Division, Indira Gandhi Centre for Atomic Research, 603 102 Kalpakkam, India
Abstract:New R 2Ti3Ge4 (R=Dy, Ho and Er) intermetallic compounds have been synthesized and characterized by X-ray diffraction and low temperature ac magnetic susceptibility, electrical resistivity and thermoelectric power measurements were carried out. The compounds crystallize in the parent, Sm5Ge4-type orthorhombic structure (space group Pnma) and lanthanide contraction is observed as one moves along the rare-earth series. The changeover from paramagnetic to antiferromagnetic phase happens at low temperatures and the ordering temperature scales with the de Gennes factor. The electrical resistivity is metallic with a negative curvature above 100 K. Thermopower displays a weak maximum at temperatures less than 50 K signifying the possible phonon and magnon drag effects.
Keywords:Intermetallic compounds  magnetic ordering  electrical resistivity  thermoelectric power
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