| 超微半扁球电极上循环扫描可逆波理论及其验证 |
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| 引用本文： | 刁国旺,李亮,张祖训.超微半扁球电极上循环扫描可逆波理论及其验证[J].化学学报,1997,55(6):570-577. |
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| 作者姓名： | 刁国旺 李亮 张祖训 |
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| 作者单位： | 南京大学化学系.南京(210008) |
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| 基金项目： | 国家自然科学基金，长春应用化学研究所电分析化学研究开放实验室资助课题 |
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| 摘 要： | 本文提出了超微半扁球电极上循环伏安扫描可逆波理论,对不同p,g参数时电流、电位的性质进行了详细的讨论,并用汞超微半扁球电极在四氯苯醌-四丁基高氯酸铵-乙腈体系中的实验对理论进行了验证,实验结果与理论相符。
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| 关 键 词： | 可逆波理论 微电极 循环伏安法 乙腈 四丁基高氯酸铵 四氯苯醌 |
Theory of cyclic voltammetric reversible wave on oblate hemispheroid ultramicroelectrode and its verification |
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| Diao Guowang,Li Liang,Zhang Zuxun.Theory of cyclic voltammetric reversible wave on oblate hemispheroid ultramicroelectrode and its verification[J].Acta Chimica Sinica,1997,55(6):570-577. |
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| Authors: | Diao Guowang Li Liang Zhang Zuxun |
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| Institution: | Nanjing Univ, Dept Chem.Nanjing(210008) |
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| Abstract: | The theory of cyclic voltammetric revresible wave on an oblate hemispheroid ultramicroelectrode has been described in this paper. The behaviours of curent-potential curve at different p and g have been discussed in detail. In order to verify the theory, the experiments were carried out on different mercury hemispheoid microelectrode with TCBQ-TBAP-acetonitrile system. The experimental results agreed with the theoretical ones. |
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| Keywords: | MICROELECTRODE CYCLOVOLTAMGRAPH ACETONITRILE CHLORANIL |
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