Tunable single-site ruthenium catalysts for efficient water oxidation |
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Authors: | Bernet Lucile Lalrempuia Ralte Ghattas Wadih Mueller-Bunz Helge Vigara Laura Llobet Antoni Albrecht Martin |
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Affiliation: | School of Chemistry & Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland. |
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Abstract: | The catalytic water oxidation activity of mononuclear ruthenium complexes comprising a pyridine-functionalized abnormal triazolylidene ligand can be adjusted by modification of the triazolylidene substituents, which is readily achieved through click-type cycloaddition chemistry, affording some of the most active ruthenium catalysts known thus far for water oxidation (TONs > 400, TOFs close to 7000 h(-1)). |
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