New environmentally friendly catalysts containing Pd-interstitial carbon made from Pd-glucose precursors for ultraselective hydrogenations in the liquid phase |
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| Authors: | Chan Chun Wong Aaron Xie Yaling Cailuo Nick Yu Kai Man Kerry Cookson James Bishop Peter Tsang Shik Chi |
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| Affiliation: | Wolfson Catalysis Centre, Department of Chemistry, University of Oxford, Oxford, OX1 3QR, UK. |
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| Abstract: | We report a novel preparation of a Pd nanocatalyst modified with subsurface C via blending a glucose precursor at the molecular level: the catalyst is demonstrated for the first time to be stereoselective in the hydrogenation of alkynes to cis-alkenes in the liquid phase. |
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