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The frustrated Lewis pair induced formation of a pentafulvene [6 + 4] cycloaddition product
Authors:Mömming Cornelia M  Kehr Gerald  Fröhlich Roland  Erker Gerhard
Institution:Organisch-Chemisches Institut der Universit?t Münster, Corrensstrasse 40, 48149 Münster, Germany.
Abstract:The frustrated Lewis pair Mes(2)P-CH(2)CH(2)-B(C(6)F(5))(2) reacts with excess 6,6-dimethylpentafulvene to yield a P/B-Lewis pair addition product to an elusive pentafulvene 6 + 4] cycloaddition dimer. This observation may open a new field of utilization of frustrated Lewis pair chemistry.
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