The frustrated Lewis pair induced formation of a pentafulvene [6 + 4] cycloaddition product |
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Authors: | Mömming Cornelia M Kehr Gerald Fröhlich Roland Erker Gerhard |
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Institution: | Organisch-Chemisches Institut der Universit?t Münster, Corrensstrasse 40, 48149 Münster, Germany. |
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Abstract: | The frustrated Lewis pair Mes(2)P-CH(2)CH(2)-B(C(6)F(5))(2) reacts with excess 6,6-dimethylpentafulvene to yield a P/B-Lewis pair addition product to an elusive pentafulvene 6 + 4] cycloaddition dimer. This observation may open a new field of utilization of frustrated Lewis pair chemistry. |
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