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Energy transfer from Sm3+ to Er3+ in zinc phosphate glass
Authors:B C Joshi  Bhawna Khulbey  Deepak Upreti and Charu Chandra Dhaundiyal
Institution:(1) Faculty of Earth Sciences, Univerity of Silesia, ul. Będzińska 60, 41-200 Sosnowiec, Poland;(2) Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Ok?lna 2, 50-422 Wrocław, Poland;(3) Center of Polymer and Carbon Materials, Polish Academy of Sciences, M. Skłodowskiej-Curie 34, 41-819 Zabrze, Poland
Abstract:A study of energy transfer from samarium to erbium ions in zinc phosphate glass has been performed for a range of donor (1.0 wt% fixed) and acceptor concentrations ranging from 0.2 wt% to 1.2 wt%. The intensity of emission spectra of Sm3+ ions in the presence of Er3+ ions shows an overall decrease, thereby suggesting a non radiative energy transfer from Sm3+ ions to Er3+ ions. The interaction mechanism between the donor and acceptor ions is found to be mainly electric dipole-dipole in nature. The parameters required for the quantitative study of energy transfer e.g. energy transfer efficiencies, transfer probabilities, critical transfer distances have been computed.
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