Oxidative transformations of 2,4-dioxo-3-(3-hydroxybutyl)-1,2,3,4,6,7-hexahyidro-11bH-benzo[a]quinolizine |
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| Authors: | A A Akhrem A M Moiseenkov V S Malishevskii |
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| Institution: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR;(2) Institute of Physical and Organic Chemistry, Academy of Sciences of the Belorussian SSR, USSR |
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| Abstract: | Conclusions The oxidation of 2,4-dioxo-3-(3-hydroxybutyl)-1,2,3,4,6,7-hexahydro-11bH-benzoa]quinolizine with either the Sarett complex or Jones reagent gives predominantly 5-oxo-2-methyl-2,3,7,8-tetrahydro-4H,5H-benzoa]pyrano2,3-g]quinolizine, while oxidation with CrO3 in AcOH solution gives 8,9,14-trioxo-12-methyl-5,6,8,9,10,11,15,15a-octahydro-13-oxa-12H,14H-azepino2,1-a]isoquinoline.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1611–1614, July, 1973. |
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