Chloroacetonylation of CC double bonds promoted by manganese(III) acetate |
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| Authors: | Cagatay Dengiz Raşit Çalışkan Metin Balci |
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| Affiliation: | 1. Middle East Technical University, Department of Chemistry, 06800 Ankara, Turkey;2. Department of Chemistry, Süleyman Demirel University, 32260 Isparta, Turkey |
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| Abstract: | The addition of acetylacetone to alkenes was performed using Mn(OAc)3·2H2O in the presence of HCl. The intermediate formed was trapped by chloride. Removal of one of the acetyl groups with ammonia under very mild conditions provided compounds derived from chloroacetonylation of the double bonds. |
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