Synthesis and specific solvatochromism of D–π–A type pyridinium dye |
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Authors: | Yousuke Ooyama Kohei Kushimoto Yuichiro Oda Daisuke Tokita Naoya Yamaguchi Shogo Inoue Tomoya Nagano Yutaka Harima Joji Ohshita |
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Institution: | Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan |
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Abstract: | Donor–π–acceptor (D–π–A) type pyridinium dye bearing an iodide ion as the counter anion that has been newly synthesized showed specific solvatochromism, leading to large bathochromic shift of absorption band in halogenated solvents: the bathochromic shifts of the D–π–A type pyridinium dye in halogenated solvents are larger than those of the non-halogenated solvents of low ?r values. Investigation of absorption spectral measurement, 1H NMR measurements, and semi-empirical molecular calculations (AM1 and INDO/S using the SCRF Onsager Model) revealed that the intramolecular charge transfer (ICT) characteristics of the D–π–A type pyridinium dye became stronger in the halogenated solvents. On the basis of the experimental results and the theoretical calculations, the influences of halogenated solvent on the large bathochromic shift of D–π–A type pyridinium dye are discussed. ©2012 Elsevier Science. All rights reserved. |
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