Direct oxidative phosphonylation of amines under metal-free conditions |
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| Authors: | Haolong Wang Xincheng Li Fan Wu Boshun Wan |
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| Affiliation: | Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China |
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| Abstract: | Direct oxidation coupling of tertiary amines and dialkyl- or diphenyl-substituted phosphonates was developed. The reaction was mediated by DDQ under room temperature. Various phosphonates and N-aryl tetrahydroisoquinolines were tolerated in this reaction, and α-aminophosphonates were obtained with up to 99% yield. |
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