Enantiospecific first total synthesis of (6S,7R)-silphiperfolan-6-ol |
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| Authors: | A Srikrishna Gopalasetty Nagaraju Vishal M Sheth |
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| Institution: | Department of Organic Chemistry, Indian Institute of Science, Bangalore 560012, India |
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| Abstract: | Enantiospecific first total synthesis of the angular triquinane sesquiterpene (6S,7R)-silphiperfolan-6-ol has been accomplished, starting from 2-(3-isopropenyl-2-methylene-1-methylcyclopent-1-yl)acetic acid (readily available from (R)-limonene) employing an efficient, regioselective intramolecular rhodium carbenoid insertion into the CH bond of a tertiary methyl group as the key step. |
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