Selective copper-promoted cross-coupling reaction of anilines and alkylboranes |
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Authors: | Leticia Naya Marta Larrosa Ramón Rodríguez Jacobo Cruces |
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Affiliation: | Galchimia, S.L. R&D Department, Cebreiro s/n 15823 O Pino, A Coruña, Spain |
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Abstract: | Extension of the Chan–Lam N-alkylation of anilines by using alkylboranes as organoboron partners is reported. Alkylboranes, synthesized by hydroboration of styrenes, are effectively coupled with anilines, which comprises a facile method for the synthesis of highly functionalized phenethylaniline derivatives. This is the first time that alkylboranes are used in C–N copper-promoted cross-coupling reactions. |
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