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A versatile and convenient route to ketone C-pyranosides and ketone C-furanosides from unprotected sugars
Authors:Junfeng Wang  Qin Li  Zemei Ge  Runtao Li
Institution:State Key Laboratory of Natural and Biomimetic Drugs, School of Pharmaceutical Sciences, Peking University, Beijing 100191, PR China
Abstract:Both ketone C-pyranosides (in up to 97% yields) and C-furanosides (in 83–97% yields) could be prepared, respectively, from the condensations of pentane-2,4-dione and various unprotected sugars in sodium carbonate aqueous media by adjusting the reaction conditions.
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