Enantiospecific total synthesis of 15-hydroxy-5-(methoxymethoxy)crinipellin-9-one |
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| Authors: | A. Srikrishna V. Gowri |
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| Affiliation: | Department of Organic Chemistry, Indian Institute of Science, Bangalore 560012, India |
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| Abstract: | Enantiospecific total synthesis of the crinipellin mentioned in the title was accomplished. In the present synthesis cyclopentane ring in campholenaldehyde was identified as the B-ring, two intramolecular rhodium carbenoid CH insertion reactions were employed for the construction of the A and C rings, and an intramolecular Michael addition reaction was utilized for the construction of the D-ring of crinipellin. |
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