Synthesis of new di-(3-indolyl)arenes |
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| Authors: | Ibrahim F. Sengul Kasey Wood Paul K. Bowyer Mohan Bhadbhade Rui Chen Naresh Kumar David StC. Black |
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| Affiliation: | School of Chemistry, The University of New South Wales, Sydney, NSW-2052, Australia |
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| Abstract: | 1,4-Di-(3-indolyl)benzene 6 and 2,8-di-(3-indolyl)dibenzofuran 12 were synthesized from 1,4-diacetylbenzene and 2,8-diacetyldibenzofuran, respectively, via indole synthetic strategies. Investigation into the acid-catalysed formation of macrocyclic systems from these di-(3-indolyl)arenes led to the development of the 18-membered macrocycle 14 from the diindolylbenzene 6, which was capable of undergoing complexation with nickel(II) ions. |
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