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One-pot stibine modified Co2(CO)8 catalyzed reductive N-alkylation of primary amides with carbonyl compounds |
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| Authors: | Laura Rubio-Pérez Pankaj Sharma F Javier Pérez-Flores Luis Velasco J Luis Arias Armando Cabrera |
| Institution: | 1. Instituto de Química, Universidad Nacional Autónoma de México, Ciudad Universitaria, Circuito Exterior, Coyoacán 04510, México D.F, Mexico;2. Facultad de Estudios Superiores Cuautitlán, Departamento de Química, UNAM, Cuautitlán Izcalli, Estado de México 54700, Mexico |
| Abstract: | A one-pot stibine modified Co2(CO)8 homogeneous catalytic reductive N-alkylation of primary amides using aldehydes/ketones as alkylating agents, is reported. Good to excellent yields of a wide range of secondary amides are obtained (up to 97%) under relative mild conditions. |
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