E/Z product distribution in the metathesis of allyl alcohol derivatives with a first generation ruthenium-based catalyst |
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Authors: | Jonathan R. MoulinsD. Jean Burnell |
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Affiliation: | Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, Canada B3H 4R2 |
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Abstract: | Based on experiments with four simple derivatives of allyl alcohol, it has been shown that the product of cross-metathesis as mediated by a ‘first generation’ ruthenium catalyst increases in its proportion of the E-isomer as the reaction progresses. This increase is due to equilibration, which is also mediated by the ruthenium catalyst. |
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Keywords: | Cross-metathesis Alkene First generation ruthenium catalyst Equilibration |
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