Syntheses and crystal structures of heterometallic complexes [{Cu(en)2}2{Cu(en)2(NH3)}{M4Te4(CN)12}]·5H2O (M = Mo,W) |
| |
| Authors: | Kalinina I. V. Samsonenko D. G. Nadolinnyi V. A. Lipkowski J. Fedin V. P. |
| |
| Affiliation: | (1) A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090 Novosibirsk, Russian Federation;(2) Institute of Physical Chemistry, Polish Academy of Sciences, 44/52 ul. Kasprzaka, 01 224 Warsaw, Poland |
| |
| Abstract: | Evaporation of aqueous ammonia solutions of K7[Mo4Te4(CN)12]·12H2O or K6[W4Te4(CN)12]·5H2O, copper(ii) chloride, and ethylenediamine afforded the isostructural heterometallic complexes [{Cu(en)2}2{Cu(en)2(NH3)}{M4Te4(CN)12}]·5H2O (M = Mo or W), which were characterized by IR and ESR spectroscopy and X-ray diffraction analysis. |
| |
| Keywords: | clusters molybdenum tungsten tellurium copper X-ray diffraction analysis IR spectroscopy ESR spectroscopy |
| 本文献已被 SpringerLink 等数据库收录！ |
|
