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Reaction of iron pentacarbonyl with ethyl dichloroacetoacetate and dichloroacetylacetone
Authors:F. K. Velichko  R. A. Amriev  Z. A. Abdulkina  S. I. Kuznetsov
Affiliation:(1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow
Abstract:Conclusions Ethyl dichloroacetoacetate and dichloroacetylacetone react with Fe(CO)5 to form iron chelates Fe[ClC · (COR)COCH3]3 (R=OEt and Me). The structures of these chelates were elucidated by35Cl NQR, mass, and IR spectroscopy.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 478–479, February, 1985.
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