Metal complexes of 2-hetarylindandiones-1,3 |
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Authors: | E. V. Sennikova A. S. Antsyshkina G. G. Sadikov A. V. Bicherov O. Yu. Korshunov G. S. Borodkin M. S. Korobov V. S. Sergienko N. N. Kharabaev A. D. Garnovskii |
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Affiliation: | (1) Institute of Physical and Organic Chemistry, South State University, Rostov-on-Don, 344104, Russia;(2) Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia;(3) South Scientific Center, Russian Academy of Sciences, Rostov-on-Don, 344006, Russia |
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Abstract: | The chelate and molecular complexes of 2-(2-benzazolyl, perimidyl)-indandiones-1,3 were synthesized for the first time. The structures of the ligands (tautomeric forms) and complex compounds were determined from the X-ray diffraction, 1H, 13C NMR, and IR data and the quantum-chemical calculations (RHF SCF in 6-31 G** basis). |
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