Effect of substituent on the mechanism of oxidation of anilines by acidic iodate. A kinetic study |
| |
| Authors: | P Manikyamba and E V Sundaram |
| |
| Institution: | (1) Department of Chemistry, University College, Kakatiya University, 506 009 Warangal, India |
| |
| Abstract: | The nature of the substituent is found to exhibit a profound influence on the mechanism of oxidation of anilides by iodate. The process appears to be smooth with electron-releasing groups, while it involves consecutive reactions with electron-withdrawing groups. Azobenzenes and quinones are obtained as the major products with electron-releasing and withdrawing groups, respectively.
                     .    -  , -   .    -, .
|
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
