Facile photo-ultrasonic assisted synthesis of flower-like Pt/N-MoS2 microsphere as an efficient sonophotocatalyst for nitrogen fixation

Semiconductor photocatalytic technology is a sustainable and less energy consuming one for nitrogen (N₂) reduction to produce ammonia (NH₃). In this study, flower-like hierarchical N doped MoS₂ (N-MoS₂) microsphere was synthesized as a photocatalyst by one-step solvothermal method, which was assembled by numerous interleaving nanosheets petals with thin thickness. Besides, Pt nanoparticles were loaded on the surface of N-MoS₂ via photo-ultrasonic reduction method. The as-prepared Pt/N-MoS₂ photocatalyst exhibited higher N₂ fixation ability than that over pure MoS₂ and N-MoS₂, which can be attributed to that the N doping narrows the band gap, and the Schottky barrier due to the existence of Pt nanoparticles improves the charge transfer and carrier separation. The reduction of N₂ with ultrasonic irradiation was also investigated under visible light irradiation to evaluate the sonophotocatalytic activity of the Pt/N-MoS₂ microsphere. The results showed that the N₂ reduction rate of sonophotocatalysis (133.8 µmol/g_(cat)h) was higher than that of sonocatalysis and photocatalysis, which can be ascribed to the synergistic effect of ultrasound and visible light irradiation. The effects of catalyst dosage, ultrasonic power and ultrasonic pulse on the photocatalytic efficiency were also studied. Meanwhile, a possible mechanism for improved sonophotocatalytic performance was also proposed.