The dynamics of sorption of sulfuric acid by weakly basic polyacrylic anion exchangers |
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Authors: | A. V. Mamchenko and T. V. Kushnir |
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Affiliation: | (1) Dumanskii Institute of Colloid Chemistry and Chemistry of Water, National Academy of Sciences of Ukraine, Kiev, Ukraine |
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Abstract: | The nonequilibrium dynamics of sorption of sulfuric acid by free base forms of Amberlite IRA-67 and Lewatite VP.OC.1072 weakly basic anion exchangers is studied. It is established that, in hydrodynamic regimes of filtration, which are typical of OH filters of the first stage of water-desalting plants, the limiting stage of sorption kinetics is inside diffusion. It is concluded that the process is correctly described by an asymptotic solution to the inside-diffusion model of sorption dynamics. Original Russian Text ? A.V. Mamchenko, T.V. Kushnir, 2009, published in Zhurnal Fizicheskoi Khimii, 2009, Vol. 83, No. 5, pp. 967–971. |
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