| 无铅和稀土的大尺寸分子基绿光荧光晶体:(C5H13ClN)2[MnCl4] |
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| 引用本文： | 蔡星伟,羌伟,赵玉媛,李红,黄翠萍,郭永春. 无铅和稀土的大尺寸分子基绿光荧光晶体:(C5H13ClN)2[MnCl4][J]. 无机化学学报, 2018, 34(2): 283-288 |
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| 作者姓名： | 蔡星伟 羌伟 赵玉媛 李红 黄翠萍 郭永春 |
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| 作者单位： | 江苏科技大学环境与化学工程学院, 镇江 212003,江苏科技大学环境与化学工程学院, 镇江 212003,江苏科技大学环境与化学工程学院, 镇江 212003,江苏科技大学环境与化学工程学院, 镇江 212003,江苏科技大学环境与化学工程学院, 镇江 212003,江苏科技大学环境与化学工程学院, 镇江 212003 |
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| 基金项目： | 江苏省自然科学基金（No.BY2016073-06）资助项目。 |
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| 摘 要： | 通过氯化锰和2-二甲氨基异丙基氯盐酸盐在溶液中的反应，制备了一类绿光分子基晶态材料：（C5H13ClN）2[MnCl4]（1）。该材料在紫外光激发后发出强烈的绿色荧光，并且热分析测试表明其具有较好的热稳定性（分解温度大于450 K）。结构和光谱分析表明其优异的光学性能归因于[MnX4]2-四面体中Mn2+的4T1（G）→6A1电子跃迁。
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| 关 键 词： | 有机-无机杂化 晶体结构 荧光性质 |
| 收稿时间： | 2017-09-18 |
| 修稿时间： | 2017-12-06 |
Lead/Rare Earth-Free Green-Light-Emitting Crystal of Molecular-Based Hybrid Compound: (C5H13ClN)2[MnCl4] with Large Crystal Size |
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| CAI Xing-Wei,QIANG Wei,ZHAO Yu-Yuan,LI Hong,HUANG Cui-Ping and GUO Yong-Chun. Lead/Rare Earth-Free Green-Light-Emitting Crystal of Molecular-Based Hybrid Compound: (C5H13ClN)2[MnCl4] with Large Crystal Size[J]. Chinese Journal of Inorganic Chemistry, 2018, 34(2): 283-288 |
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| Authors: | CAI Xing-Wei QIANG Wei ZHAO Yu-Yuan LI Hong HUANG Cui-Ping GUO Yong-Chun |
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| Affiliation: | School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China,School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China,School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China,School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China,School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China and School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China |
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| Abstract: | |
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| Keywords: | organic-inorganic hybrid crystal structure luminescence |
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