Dimethyldithiocarbamatostibane |
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Authors: | R. Egle W. Klinkhammer A. Schmidt |
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Abstract: | Dimethylaminodithiocarbamatostibanes The Halogeno-bis(dimethylaminodithiocarbamato)stibanes (dtc)2SbCl 2 and (dtc)2SbBr 3 are prepared from (dtc)3Sb 1 . Reaction of 2 and 3 resp. with CF3SO3SiMe3 yields the ionic compounds (dtc)2Sb+CF3SO3? 4 and (dtc)2Sb+]2Br?(CF3SO3?) CH2Cl2 5 by elimination of Me3SiHal. The molecular structure of 4 is determined by X-ray analysis. The vibrational and mass spectra of 1–5 are reported and briefly discussed. |
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Keywords: | Ionic antimony(III)-dithiocarbamates syntheses structure vibrational and mass spectra |
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