Spectroscopy of DABCO-rare-gas and DABCO-DABCO van der Waals complexes |
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Authors: | G van den Hock D Consalvo D H Parker J Reuss |
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Institution: | 1. Department of Molecular and Laser Physics, University of Nijmegen, Toernooiveld 1, 6525ED, Nijmegen, The Netherlands
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Abstract: | The excited electronic origin bands of several DABCO containing van der Waals complexes have been observed via (1+1) resonance enhanced multi-photon ionization. Sharp resonances with widths of about 3 cm–1 are seen for DABCO-Rg
n=1,2,3 (Rg is Ar, Kr or Xe), for the DABCO-DABCO dimer and for DABCO-DABCO-Ar. The origins of the rare-gas complexes are blue shifted with respect to the monomer origin. Broad features originating from DABCO-Rg
n
complexes with highn, appear to higher energies than the complex origins, with widths of 120 cm–1. |
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Keywords: | PACS" target="_blank">PACS 33 20 Lg 36 40 +d |
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