Study of the steps of acrolein oxidation over a vanadium-molybdenum catalyst |
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| Authors: | G. Ya. Popova T. V. Andrushkevich G. A. Metalkova |
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| Affiliation: | (1) Institute of Catalysis, Novosibirsk, USSR |
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| Abstract: | Acrolein is oxidized to acrylic acid over a V–Mo catalyst by lattice oxygen, while the formation of CO2 also involves gas phase oxygen. The steady state of catalyst reduction is about 5% monolayer and is characterized by an oxygen binding energy of 61 kcal/mol.
              V–Mo-      ,  CO2      .     5%   61 /.
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