A new type of stabilized carbonucleophiles with a carboranyl group |
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| Affiliation: | 1. Department of Industrial Chemistry, Kyungpook National University, Taegu, 702-701 South Korea;2. Institute of Organoelement Compounds of Russian Academy of Sciences, Vavilov 28, Moscow 117813 Russian Federation;1. Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China;2. State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China;1. College of Chemistry and Molecular Sciences, Engineering Research Center of Organosilicon Compounds and Materials, Ministry of Education, Wuhan University, Wuhan 430072, China;2. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai 230021, China;1. CCNU-uOttawa Joint Research Centre, Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China;2. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, China |
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| Abstract: | Palladium-catalyzed allylation of carboranylacetic esters gives C-allyl derivatives in high yield. Thus, a new type of stabilized carbonucleophiles with the electron-withdrawing o-carboranyl group has been made. |
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