Assembling metals and clusters around an octaphosphine ligand based on N-substituted bis(diphenylphosphanyl)amines: structural characterization of dendrimer-like Co12 and Co16 branched clusters |
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| Authors: | Rodriguez-Zubiri Mireia Gallo Vito Rosé Jacky Welter Richard Braunstein Pierre |
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| Institution: | Laboratoire de Chimie de Coordination, Institut de Chimie (UMR 7177 CNRS), Université Louis Pasteur, 4 rue Blaise Pascal F-67070 Strasbourg, France. |
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| Abstract: | A polypodal ligand based on an aromatic ring decorated by four dppa-type diphosphine moieties has been used to prepare Pt(II) complexes and to assemble four tricobalt or tetracobalt carbonyl clusters, leading to centrosymmetric Co12 and Co16 "clusters of clusters" which were characterized by X-ray diffraction. |
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