The Synthesis and Properties of New Metal-free and Metallophthalocyanines Containing Four Diloop Macrocyclic Moieties |
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Authors: | AHMET BİLGİN BEYTULLAH ERTEM |
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Affiliation: | 1. Kocaeli University, Department of Science Education , Kocaeli, Turkey;2. Karadeniz Technical University, Department of Chemistry , 61080, Trabzon, Turkey |
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Abstract: | The synthesis and characterization of new metal-free (9) and metal-containing (Zn, Ni or Cu 10, 11, 12) derivatives of a symmetrically octasubstituted phthalocyanine derived from 21,22-dicyano-2,3,5,6,8,9,11,12,15,17,18,25,26,28-tetradecahydro[1,4,7,12] benzodioxadithiacyclotetradeceno[6,7-b][1,4,7,10,13]benzopentaoxacyclopentadecene (7), which was synthesized in a multi-step reaction sequence, have been described. The novel compouds have been characterized by a combination of elemental analysis, 1H and 13C NMR, IR, UV–vis and MS spectral data. |
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Keywords: | Diloop macrocycle Phthalocyanine derivatives Isoiminoindoline Nickel (II) Copper(II) Zinc(II) |
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