Synthesis of Highly Functionalized Fluorinated Porphyrins |
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| Authors: | Tomáš Bříza Martin Havlík Bohumil Dolenský Zdeněk Kejík Pavel Martásek |
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| Institution: | 1. Department of Analytical Chemistry , Institute of Chemical Technology in Prague , Technická 5, Prague 6, 16628, Czech Republic;2. First Faculty of Medicine, Charles University in Prague , Katerinská 32, Prague 2, 12108, Czech Republic |
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| Abstract: | Highly functionalized fluorinated porphyrins were synthesized by a convergent strategy. Nucleophilic substitution using fluorinated branched unit and 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin afforded highly functionalized fluorinated porphyrin 8 containing 24 fluorinated chains in the peripheral region. |
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| Keywords: | Fluorinated dendritic structure Polyfluoroalkylated porphyrin Fluorous Porphyrin core |
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